FERMANAGH, an inland county in the province of Ulster, Ireland, extending from 54° 7' to 54° 40' N. lat., and from 7° Γ to 8° 5' W. long., is bounded on the N.W. by Donegal, on the N.E. by Tyrone, on the E. by Monaghan, and on the S.W. by Cavan and Leitrim. Its greatest length N.W. and S.E. is 45 miles; its greatest breadth N.E. and S.W. is 29 miles. The area extends to 457,369 statute acres, or 714^ square miles, of which 106,530 acres are under tillage, 243,251 in pasture, 5909 in plantations, 55,248 in waste, bog, mountain, &c., and 46,431 under water. The county is divided into eight baronies: viz., Clanawley, Clankelly, Coole, Knockninny, Lurg, Magheraboy, Magherastephana, and Tirkennedy; and these are subdivided into 23 parishes, and 2183 townlands.
The chief town in Fermanagh is Enniskillen, population (1871) 5836. The only other towns of any importance are—Lisnaskea (857), Irvinestown, formerly Lowtherstown (787), Maguire’s Bridge (685), Tempo (460), Newtownbutler (418), Brookborough (390), Rosslea (371), Ederney (332), Belleek (327), Derrygonnelly (302), Kesh (296), in all of which fairs are held and post-offices established. The Irish North-Western division of the Great Northern Railway passes through the most populous portion of the county, one branch connecting Enniskillen with Clones, another connecting Enniskillen with Londonderry, via Omagh, and a third connecting Enniskillen with Bundoran....
Physical Features.— Fermanagh is situated mostly in the basin of the Erne, which divides the county into two nearly equal sections. It presents a hilly, and in many parts a somewhat sterile appearance, though in the main, and especially in the neighbourhood of Lough Erne, it is picturesque and attractive. The climate though moist is healthy, and the people generally are tall and robust. The chief mountains are Cuilcagh (partly in Leitrim and Cavan) 2188 feet high, Belmore 1312 feet, Glenkeel 1223, North Shean 1135, Tappahan 1110, Carnmore 1034. Tossett or Toppid and Turaw mountains command extensive prospects, and form striking features in the scenery of the county. But the most distinguishing feature of Fermanagh consists in the great extent of its surface being occupied by the Upper and Lower Loughs Erne, which stretch for 45 miles from S.E. to N.W. These lakes are formed by the expansion of the river Erne, which enters the county from Cavan at Wattle Bridge, and spreads out its waters in the Upper Lough, broken by innumerable islets. Contracting itself again, the river flows in a meandering course to the town of Enniskillen, where it expands itself once more in the Lower Lough, which extends in a N.W. direction for about 20 miles, till the river again issues from it a mile above Belleek. Of the two loughs the lower and larger one is most famed for its picturesque scenery. Both are dotted with many islands, the number of which has been stated as high as 199. The largest islands are Boa (or “Cow ”), Ennismacsaint, Devenish, Eagle, Innisnakill Gully, Cor, Ferney, Herring, Innismore, and Bellisle. It is navigable throughout, during the winter season, a small steamer plying between Enniskillen and Belleek. The other lakes next in size are Loughs Melvin and Macnean on the border of Leitrim, and draining into the Drowes river. The chief river is the Erne, which, rising in Cavan, passes through Belturbet, Lough Erne, and Belleek on its way to the Atlantic, into which it descends at Ballyshannon. At Belleek it forms a considerable waterfall, well known to sportsmen for its good salmon-fishing. There are several mineral springs in the county, some of them chalybeate, others sulphureous. At Belcoo, near Enniskillen, there is a famous well called Daragh Phadric, held in repute by the peasantry for its cure of paralytic and other diseases; and four miles N.W. of the same town, at a place called “the Daughton,” are natural caves of considerable size. The geological formation of the county may be described as consisting mainly of secondary limestone and yellow sandstone. In the former organic remains are plentiful, some fine specimens of encrinites being easily obtainable. A brown marble excavated at Florence Court is beautifully veined, and susceptible of a splendid polish. Grey marble has been found in the parish of Killasher. Iron and coal have also been traced in various places, but only in small quantities. The best iron ore mine is at Belleek.
Industries—Agriculture, <£'c.— With the exception of the pottery works at Belleek, Fermanagh cannot boast of any distinguishing manufactures. It is chiefly an agricultural county. Of the arable land about the one-half is devoted to pasturage. Oats and potatoes are the crops most extensively cultivated. The next in order are flax, turnips, wheat, barley, rye, beans, and pease. The following table shows the number of acres under the different crops during the years 1874 and 1877 :— [table]
The live stock (horses, cows, sheep, &c.) in the county was valued in the census of 1871 at £839,899, but this estimate was on the basis of the values fixed by the census commissioners of 1841, and is therefore much below the actual present worth, which is probably £1,500,000. From statistics prepared specially for Thom’s Almanac for 1877, it is estimated at £1,354,379. The number of live stock in Fermanagh given in the registrar-general’s annual returns during the years 1874 and 1877 is as follows :— [table]
The county in 1873 was divided among 707 proprietors, of whom 130 owned less than one acre each, or 19 per cent,—-the proportion for all Ulster being 48 per cent. The average extent of each holding was 586 acres, that of Ulster being 239 acres. The total annual rental of the land amounted to £234,634, or 11s. 5|d. per acre—that of Ulster 15s. 8∣cl More than half the whole county was in possession of ten proprietors, namely,—Marquis of Ely, Ely Lodge, 34,879 acres; Earl of Erne, Crom Castle, 31,389; Earl of Enniskillen, Florence Court, 29,635; Sir V. H. Brooke, Bart, Colebrook Park, 27,994; Mervyn Archdall, Castle Archdall, 27,410; John Madden, Roselea Manor, 14,074; J. G. Irvine, Killadeas, 11,388; J. G. Porter’s representatives, 11,015; Church Temporalities Commissioners, 10,357; and Hugh de Fellenberg Montgomery, 7996.
Education, eke.— According to the census of 1871, the number of persons in the county over five years of age who could read and write was 41,226; 18,349 could read but could not write, and 22,758 could neither read nor write. There were 10 persons who spoke Irish only, and 349 who spoke both Irish and English. There were two superior schools, having a total of 94 pupils in attendance, all Protestants. On the 31st December 1876 there were on the rolls of the national schools 16,640 pupils, of whom 9720 were Roman Catholics, 6321 Protestant Episcopalians, 278 Presbyterians, and 321 of other persuasions. At the same date at the Enniskillen model school there were 339 pupils on the rolls, of whom 229 were Protestant Episcopalians, 33 Presbyterians, 18 Roman Catholics, and 59 of other persuasions. In Fermanagh there are neither reformatory nor industrial schools.
Administration, <L ’ c.— Fermanagh returns three members to pari lament—two for the county, undone for the borough of Enniskillen. The assizes are held at Enniskillen, quarter sessions at Enniskillen and Newtownbutler, and petty sessions at eleven places throughout the county. Fermanagh is within the Belfast military district. The barrack stations are at Enniskillen and Belleek, Ecclesiastically it belongs for the most part to the diocese of Clogher. The county jail and the county infirmary are at Enniskillen; but the district lunatic asylum is at Omagh (in Tyrone), serving for the two counties, Fermanagh and Tyrone. The poor law union workhouses for the county are at Enniskillen, Irvinestown, and Lisnaskea.
Population.— The population of Fermanagh steadily increased up till the year 1841. The famine and subsequent emigration intervening between that year and the next parliamentary census (1851), the population showed a decrease at the latter date of about 25 per cent, and since 1851 the decrease has continued. The exact decrease during the 30 years 1841 to 1871 is 40 ’ 69 per cent. In 1841 the population was 156,481; in 1851," 116,047; in 1861, 105,768; in 1871, 92,794; and on the 31st December 1876 it was estimated at 91,188. From the 1st May 1851 to 31st December 1876, the total number of emigrants from Fermanagh was 34,776, or an average of 1337 per annum. In 1871 55 per cent, of the population were returned as Catholics.
History and Antiquities.— According to Ptolemy, the aborigènes of this county were the Hrdini. By the ancient Irish it was called Feor-rnagh-Eanagh y or the “country of the lakes” (lit. “the mountain-valley marsh district ”); and also Magh-uire, or “the country of the waters.” It was divided into two large portions—the one called Targoll, the other Rosgoll. The latter was occupied by the Guarii, the ancestors of the MacGuires or Maguires, a name still very common in the district. This tribe or family was so influential that for centuries the county was called after them Maguire’s Country, and one of the towns still existing bears their name, Maguire’s Bridge. Fermanagh was one of the six countiee which reverted to the crown at the time of the flight of the earls of Tyrone and Tyrconnell, and which were included in the well known scheme of colonization of James I., the Plantation of Ulster. Among the principal Scotch and English settlers at the period of the Plantation were Sir Stephen Butler, Sir Wm. Cole, John Archdall, and Sir Gerard Lowther, from whom some of the towns and villages in the county derived their names, and whose descendants form the leading gentry to the present day. During the revolution of 1688 Fermanagh rendered signal service to the cause of William III. by the gallant stand which its yeomen made against the Irish army, and their descendants possess so much of the military spirit of their forefathers as to make the title “Fermanagh men” still Bynonymous with bravery and loyalty to the constitution. In the year 1689 battles were fought between William III.’s army and the Irish under Macarthy (for James ∏.) at Lisnaskea (26th July) and Newtownbutler (30th July). The chief place of interest to the antiquary is Devenish Isle in Lough Erne, about 2 J miles N.W. from Enniskillen. It contains about 80 acres of very fertile pasture land, and has long been celebrated for its romantic situation and ecclesiastical ruins. Near the remains of the abbey of St Mary, founded in the 6th century by St Laserian (called also Molaisse or Molush), is one of the best specimens of Ireland’s round towers. It is 82 feet high and
49 in circumference, with an ingeniously constructed conical roof. About half a century ago it was carefully repaired, and is now in excellent preservation. Pursuant to “Tho Irish Church Act, 1869,” both the round tower and the abbey have been vested in the secretary of the commissioners of public works in Ireland to be preserved as national monuments. In various places throughout the county may be seen the ruins of several ancient castles, Danish raths, and tumuli, in which last have been found at times urns and stone coffins. At Wattlebridge, near Newtownbutler, are the remains of a Druidical temple. (w. e. c.)
[1,928 words — estimated reading time: 12 minutes]
FERMAT, Pierre de (1601-1665), a famous mathematician, was born at Beaumont-de-Lomagne near Montauban. While still young he, along with Pascal, made somo discoveries in regard to the properties of numbers, on which he afterwards built his method of calculating probabilities. He discovered a simpler method of quadrating parabolas than that of Archimedes, and a method of finding the greatest and smallest ordinates of crooked lines analogous to that of the then unknown differential calculus. His method of maxima and minima brought him into conflict with Descartes, but the dispute was due chiefly to a want of explicitness in the statement of Fermat. Fermat was for some time councillor for the parliament of Toulouse, and in the discharge of the duties of that office he was distinguished both for legal knowledge and for strict integrity of conduct. Though the sciences were the principal objects of his private studies, he was also an accomplished general scholar and an excellent linguist. He died at Toulouse in 1665. He left a son, Samuel de Fermat, who was a man of some learning, and published translatione of several Greek authors....
The Opera Mathematica of Fermat were published at Toulouse, in 2 vols, folio, 1670 and 1679; they have now become very scarce. The first contains the “Arithmetic of Diophantus/’ with notes and additions. The second includes a “Method for the Quadrature of Parabolas,” and a treatise “onMaxima and. Minima, on Tangents, and on Centres of Gravity,” containing the same solutions of a variety of problems as were afterwards incorporated into the more extensive method of fluxions by Newton and Leibnitz. In the same volume are treatises on “Geometric Loci, or Spherical Tangencies,” and on the “Rectification of Curves,” besides a restoration of “Apollonius’s Plane Loci,” together with the author’s correspondence addressed to Descartes, Pascal, Roberval, Huygens, and others.
[308 words — estimated reading time: 2 minutes]
FERMENTATION, a chemical term, which, in accordance with its derivation from fervere (to boil), was originally applied indiscriminately to all chemical changes involving the effervescence of a liquid, but which, in its modern acceptation, has in itself nothing at all to do with effervescence, being used to designate a peculiar class of metamorphoses which certain complex organic materials are liable to, and of which the well-known change which grape juice undergoes when it “ferments” into wine, the souring of wine or milk, and the putrefaction of animal or vegetable matter may be cited as familiar examples....
What in all these and similar processes strikes the ordinary observer as something particularly characteristic is their spontaneity: sweet milk turns sour, grape juice passes into wine, wine into vinegar, vinegar into a foul insipid fluid—without the application or addition from without of any agent or reagent; but the “spontaneity” in the eyes of the chemical investigator does not go far. All chemical reactions are spontaneous; and wherever a ease occurs of two things acting upon each other, it makes no difference whether one of them be added, say, to the solution of the other from a bottle, or whether it were present in the liquid from the first. What caused chemists to group together fermentative changes as a class of phenomena different from ordinary reactions was the fact that wherever they succeeded in reducing the phenomena to a degree of simplicity sufficient for translating the respective reaction into an equation, this equation, though perfectly correct in the sense of chemical arithmetic, appeared to assert something which ran contrary to the known chemical tendencies of the substances concerned. To explain this by an example, let us take the case of the souring of milk, a fermentation which, when stripped of what, from the purely chemical standpoint, would appear unessential, involves only one reaction, which consists in this, that the milk sugar of the milk, by a mere rearrangement of its ultimate ingredients, passes into lactic acid, according to the equation C 12 H 22 O 11 .H 2 O = 4C 3 H 6 O 3 .
Milk Sugar. Lactic Acid.
Now, this in itself is nothing exceptional. A solution of cyanate of ammonia (NCOH.NH 3 ) is no sooner prepared than it passes into one of urea CO(NH 2 ) 2 j cyanic acid, (NCHO) when left to itself, soon passes into cyamelide, just as the milk sugar of the milk passes into lactic acid. But there is this great difference, that this latter change cannot be realized, under any known set of conditions, in a solution of pure milk sugar in pure water. And so it is in all other analogous cases. But this comes to the same as saying that fermentations, as a class of chemical reactions, are characteristically non-spontaneous, and consequently must be caused by reagents, although these reagents have no place in the mere balance-sheet of the reaction. In fact, experience shows that no fermentable chemical species will ferment except in presence of water, and unless it be kept by means of that water in direct contact with some specific “ferment,” which, although it contributes nothing to the substance of the products which figure in the equation, nevertheless induces the reaction “by its presence,” as the phrase goes. The presence alone, of course, will not do. It is simply inconceivable that a reagent should act chemically unless it were itself in a state of chemical change, although this change may be (and with some ferments probably is) a cycle of changes which always brings back the reagent to its original condition.
Of all the multitude of chemical processes which fall under our heading, vinous fermentation is the one which is by far the best known and most satisfactorily explained; and it is scarcely an exaggeration to say that the present science of the whole subject has been evolved from the study of that particular case. Hence the best course that we can adopt in this article is to begin with a popular exposition of the growth of our knowledge of vinous fermentation, which may familiarize even the general reader with the main points of the whole subject, and then to append a short epitome of the facts concerning the more important of the different fermentative changes.
Vinous fermentation means that peculiar change which all native sacchariferous juices are liable to undergo when left to themselves at the ordinary temperature, and which results in the formation of some kind of “wine.” The general course of the phenomena being the same in all cases, we shall assume in what follows that it is grape juice we have to deal with. Such juice, as is well known, when recently prepared, forms an intensely sweet yellowish liquid, which, if it is not so by nature, may be rendered perfectly limpid and transparent by filtration through bibulous paper. Grape juice when left to itself, after having been thus clarified, may remain unchanged for an indefinite time, but when mixed with ever so little of unfiltered juice, it is sure sooner or later to undergo a change, which manifests itself in the appearance of a turbidity in the liquid. This turbidity is owing to two causes, namely, (1) the evolution of carbonic acid, and (2) the formation within the liquid of a finely-divided solid, which, through the gas-evolution, is partly kept in suspension, partly thrown up to the surface as a scum, and which is known by the name of “yeast.” The process, from an almost imperceptible beginning, gradually develops into a more and more vivid effervescence (which not unfrequently assumes the character of a violent ebullition), the yeast at the same time becoming more and more abundant; and when a sufficient quantity of “must” is operated on, the temperature of the fermenting mass soon rises perceptibly beyond that of the surrounding air. Sooner or later of course the reaction reaches a climax, from which onwards it gradually loses in intensity until at last it dies out. The yeast then settles down as a slimy deposit, above which there is left a clear yellow liquid, which, instead of the originally sweet, now has a “vinous” taste, and is endowed with that well-known physiological action characteristic of “fermented liquors.” Chemically the change in the nature of the liquid consists substantially in this, that the sugar has mostly or perhaps wholly disappeared, and given place to a corresponding percentage of a volatile inflammable liquid called alcohol. To any one who has a real knowledge of these facts it must necessarily suggest itself as a highly probable hypothesis that it is the destroyed sugar which has furnished the ingredients for the formation of the carbonic acid and of the alcohol, while most persons will be inclined to look upon the yeast as a bye product formed from the secondary constituents of the juices.
This view, which is endorsed substantially by our present knowledge of the matter, one is inclined to think should have forced itself even at the earliest times upon the minds all who reasoned on the process as a material metamorphosis. But although now-a-days everybody looks almost instinctively upon chemical reactions as nothing more than rearrangements of the ultimate ingredients of the bodies concerned, which ingredients in themselves are, as a matter of course, assumed to be uncreatable and indestructible, we must not forget that this notion dates back only to the time of Boyle, and that is not much longer than air, and gases generally, have been recognized as species of weighable matter. Hence for many centuries the carbonic acid was not recognized even by chemists as forming a factor in the chemical reaction; it was known only as an effervescence, a phenomenon pure and simple, not as a substance. Van Helmont (born in 1577) was the first to show that the gas which rises from fermenting “must” is different from air, and identical with the gas sylvestre formed in the combustion of charcoal and in the calcination of limestone. Long before Van Helmont’s time, the “alcohol” had been recognized as a definite kind of matter. The art of concentrating the intoxicating principle of wine by distillation, in fact, was known and practised industrially in the 8th century; and nobody could practise this art without finding out that a spirit can be strengthened by repeated distillations, with elimination of water. But it was only about the 13th century that chemists learned to remove all the water from spirits of wine, and thus to prepare “absolute,” that is, pure alcohol.
Ordinary cane sugar and honey were known to the ancients; and chemists from the earliest times took it for granted that these two substances and the sweet principles in fruit juices must be closely related to one another. It is also an old experience that cane sugar or honey when added to grape juice ferments with the sugar originally present in the latter. But the idea that the differences between the several kinds of sugar are owing to the existence of a number of distinct chemical species is comparatively new, and it is only in the course of the present century that the problem of isolating these several species has been satisfactorily solved.
But to return to our proposition; plausible as it is as an hypothesis, to be able to test even its potential correctness, we must know the weights of alcohol and carbonic acid produced in the fermentation of a given weight of sugar, and know also the quantitative elementary compositions of the three substances. Lavoisier was the first to make experiments for supplying these data, which, in fact, could not reasonably have been attempted by anybody before him, as it is he to whom we owe our knowledge of the qualitative elementary composition of the substances concerned, and indeed of organic substances generally.
Before giving his numbers, it may be stated that he regarded acetic acid (a small quantity of which is present in most wines) as, like alcohol and carbonic acid, a constant product of vinous fermentation. According to Lavoisier, 95 , 9 parts of cane sugar in fermenting yield [table]
And according to his elementary analysis of these substances, the proportions by weight are— [table]
From these numbers Lavoisier concluded (and he was quite justified in doing so, considering the imperfections of his methods of analysis) that sugar in fermenting simply breaks up into these three substances, without any access of matter from without. But if he thus managed to arrive at what we now know to be a substantially correct conclusion, this can be credited to him (if at all) only as a happy stroke of divinatory genius, as his numbers are all of them monstrously incorrect, the errors going far beyond what even, with his necessarily imperfect method, could be tolerated as “observational errors.” Lavoisier’s numbers were subsequently corrected by Gay-Lussac according to his own analyses of sugar, alcohol, and carbonic acid. His results, which have remained unimpugned to the present day, may be stated, with substantial correctness, to have been as follows :—
In vinous fermentation very nearly one-third of the carbon goes off as carbonic acid, while the rest passes into the alcohol; and reducing to 1, 2, and 3 parts of carbon, we have [table]
The agreement being by no means satisfactory, Gay-Lussac suspected that his analyses of sugar were infected with unobserved errors, and he corrected his figures so as to make them agree with those given above opposite to “Sums.” These values, when measured by the customary units (namely C for twelve parts of carbon, H for one part of hydrogen, O for sixteen parts of oxygen), assign to sugar the very simple formula C 1 H 2 O 1 leading to an equally simple equation for the reaction, which is :—
6×(CH 2 O) = C β H la O β = 2C 2 H 6 O + 2CO 2 ; i.e., 180 of sugar gives 2 × 46 of alcohol+ 2 × 44 of carbonic acid; or 45 ,, ,, 23 ,, + 22 ,, ,,
This equation is still looked upon as substantially correct, though not in Gay-Lussac’s sense. It is so, if by sugar we understand either of the tw o kinds of “glucose” which form the bulk of the sweetening principles in fruit juices, and which are composed according to the formula C 6 H 12 O 6 . Cane sugar, as Dumas and Boullay showed, really has the composition following from Gay-Lussac’s analysis, which, as is easily seen, corresponde to the formula C 12 H 22 O 11 = 2C 6 H 12 O 6 - H 2 O, where H 2 O means the elements of 18 parts of water; and these 18 parts of water, as Dumas and Boullay showed, actually are taken up in the fermentation of C 12 H 2θ O n = 324 parts of cane sugar.
Gay-Lussac’s equation being, as we said, only substantially correct, we must now state the qualifications implied. Schmidt of Dorpat found in 1847 that vinous fermentation always results in the formation of small quantities of succinic acid. Guerin Vary showed, by quantitative experiments, that in the fermentation of glucose the alcohol and carbonic acid produced account only for about 96 , 3 per cent, of the glucose. And the present writer happens to know that a certain German apothecary made the interesting discovery that wines, beside the unfermented remnant of glucose that may be left, may contain an unfermentable sweet principle which he recognized as glycerine. These observations, however, were little heeded until Pasteur, in a now classical memoir, proved that glycerine and succinic acid are constant products of normal vinous fermentation, the correct balance sheet of the reaction, according to him, being as follows :—100 parte of cane sugar, in fermenting, pass into 105 ’ 4 parte of glucose, which then break up, yielding (approximately) of [table]
But even this is not quite an exhaustive statement, a small portion of the sugar always passing into the form of higher alcohols (“fusel-oil”) and compound ethers.
Vinous fermentation, then, is a far more complex reaction than Gay-Lussac imagined; but it still remains true that all the products formed are derived from the dissociation of the sugar. What is it that brings about this singular decomposition! We call it a singular reaction, because it is one which sugar has never been seen to undergo when subjected by itself or as an aqueous solution to the action of heat or electricity or any ordinary reagent. And we have theoretical grounds for presuming that the reaction is not likely ever to be realized by some “reagent” that has not yet been tried. According to many experiences, an arithmetically possible reaction is the more likely to be realized the greater the heat evolution which, supposing it were realized, it would involve. Now, the reaction formulated in Gay-Lussac’s equation C β H 12 O 6 = 2CO 2 + 2C 2 H 6 O, as Professor Dewar pointed out some years ago, supposing dry sugar could be made thus to split up, would yield only an insignificant amount of heat, if any. Actual fermentation does involve a liberation of heat, as we know, but the quantity of heat per unit weight of sugar destroyed, according to Dewar’s experiments, amounts only to about 83 heat-units, which can be accounted for as being produced by the hydration of the alcohol formed, and, at any rate, is too small to characterize the decomposition of sugar into carbonic acid and alcohol as being at all of itself a probable reaction. Even the somewhat higher result previously arrived at by Dubrunfaut, namely, 135 heat-units per unit of sugar, cannot affect this conclusion. Before going further let us take an exact survey, from the chemical standpoint, of the conditions which are known to favour or impede the actual process.
(1.) Pure solutions of cane sugar or glucose do not ferment under any circumstances.
(2. ) Many kinds of impure sugar solutions, such as grape juice, brewers’ wort, &c., do ferment. The range of temperatures most favourable to this process lies between about 20* and 24* C. (or 68° and 75° F. ). But even grape juice does not ferment at temperatures lying too close to the freezing-point, nor does it fermentat temperatures exceeding a certain limit, which lies at about 60° C. (140 δ F.). The most lively fermentation comes to a stop when the liquid is boiled, and, after cooling, it takes a longer or shorter time before it resumes.
(3.) Grape juice which has been strengthened by evaporation or addition of sugar from without, does not ferment, when the ratio of water to sugar falls below a certain limit-value.
(4.) Fermentation is impeded and may be entirely stopped by addition of alcohol. Hence the wines produced from the rich juices of southern grapes always contain unfermented sugar.
(5.) Fermentation may be stopped more or less completely by addition to the liquid of even small quantities of certain reagents called antiseptics. Of these corrosive sublimate (and many other heavy metallic salts), sulphuric acid, sulphurous acid, bisulphide of carbon, and carbolic acid may be mentioned as examples.
(6.) Perfectly pure grape juice does not ferment, unless the process has been started by at least temporary contact with ordinary air. This cardinal fact was discovered by Gay-Lussac in a now classical series of experiments. He caused clean grapes to ascend through the mercury of a large barometer into the Toricellian vacuum, where he crushed them by means of the mercurial column. The juice thus produced and preserved remained unchanged; but the addition to it of ever so small an air-bell (as a rule) induced fermentation, which, when once started, was always found to take care of itself.
(7.) Ordinary vinous fermentation always involves the formation of yeast. This is the most important of positive facts made out.
(8.) The rate at which a fermentation progresses is (in a limited sense) determined by the quantity of yeast present within the liquid.
(9.) Spontaneous fermentation of grape juice is always slow in beginning; addition of yeast from without starts it immediately.
From these facts it is legitimate to conclude that it is the yeast or some constituent of the yeast which somehow or other causes the sugar to break up into alcohol, carbonic acid, glycerine, and succinic acid. But what is the rationale of the action? Chemically speaking, it would appear to be vain to attempt an answer without first knowing what yeast is made of in the chemical sense. Unfortunately the present state of our knowledge on this point is very unsatisfactory. All we know is that yeast is a highly complex mixture of chemical substances which may be arranged under the four heads of—(1) fats (forming about 2 per cent, of the whole); (2) cellulose (about 18 per cent.); (3) nitrogenous substances more or less closely allied to white of egg, some of them soluble, some insoluble in water (about 60 per cent.); (4) incombustible salts, which, when the yeast is burned, remain as “ash” (about 7 per cent.). According to Mitscherlich’s analysis, yeast-ash consists mainly of phosphoric acid (54 to 59 per cent.), united with potash (28 to 40 per cent.), magnesia (6 to 8 per cent.), and lime (1 to 4 per cent ). That such a complex mixture should act, chemically, as a whole cannot reasonably be assumed; chemists, accordingly, have always been unanimous in thinking that it is some one constituent or set of constituents of the yeast which constitutes the characteristic reagent in vinous fermentation; but none of them has succeeded in isolating that reagent. The only clue in this respect which we have is an important discovery of Mitscherlich’s, who showed that an aqueous extract of yeast, although capable of converting cane-sugar into glucose, does not induce fermentation in the glucose formed, whence it at once follows that the ferment must be sought for amongst the insoluble portion of the yeast.
Their non-success in isolating the vinous ferment did not prevent chemists from speculating on its mode of action. Berzelius gave it as his opinion (which was adopted by Mitscherlich and others of the leading chemists) that the action was a purely “catalytic” one. What he meant by this is best explained by an example. Peroxide of hydrogen (a compound of the elements of water and oxygen) is perfectly stable at ordinary temperatures. Add to it a mere speck of platinum black (a peculiar form of finely divided platinum), and it at once breaks up into water and oxygen, the platinum which caused the decomposition remaining unchanged. In an exactly similar manner Berzelius thought the yeast acted upon the sugar, and caused it to break up into alcohol and carbonic acid. The merit of the idea was that it apparently reduced the explanation of a seemingly complex to that of an undoubtedly simpler phenomenon. But unfortunately neither Berzelius nor any of his followers succeeded in...
[10,465 words — estimated reading time: 1 hour]
FERMO, the ancient Firmum Picenum, an archiepiscopal city of central Italy, and the chief town of a circle in the province of Ascoli Piceno, 34 miles S. by E. of Ancona. From its situation on a rocky height it commands a splendid prospect of the surrounding country, including a fine view of the Adriatic Sea. It is surrounded by old walls, and besides the cathedral possesses numerous churches and convent3, a university, and two fine collections of statuary and paintings. The ruins of the ancient Roman town, which was destroyed in the 5th century, are still to be seen, Lactantius and Galeazzo Sforza were born in Fermo. The port, Porto di Fermo, is situated on the Adriatic, about four miles from the town. The harbour is small, but there is some trade in corn, silk, and woollens. The population of Fermo in 1871 was 7002.
[145 words — estimated reading time: 1 minute]
FERMOY, a market-town of Ireland, in the East Riding of the county of Cork, is about 21 miles distant from Cork, and about 130 miles from Dublin, and is connected with both these cities by the Fermoy branch of the Great Southern and Western Railway. It is situated on the river Blackwater, which divides the town into two parts, the larger of which is on the southern bank, and there the trade of the town, which is chiefly in flour and agricultural produce, is mainly carried on. A stone bridge of 13 arches which formerly spanned the river, and which had been erected in 1689, was in the year 1866 removed, and replaced by one of strong cut stone. The town, which strikes the visitor as being exceedingly neat and clean, has several good streets, and some noteworthy buildings. Of the latter, the most prominent are the military barracks on the north bank of the river, capable of accommodating 3000 men, the Protestant Episcopal church, the Roman Catholic cathedral, St Colman’s Roman Catholic college, the convents, and the court-house. Quarter sessions are held in the town, and the muncipal affairs are managed by fifteen commissioners, who meet every alternate Wednesday. The market day is Saturday. The population in 1871 numbered 7388, 78 per cent, being Roman Catholics.
[220 words — estimated reading time: 2 minutes]
