IRON, Therapeutic uses of. The use of iron in the cure of disease dates from a very early period. Pliny speaks of its medicinal effects, and there is reason for believing that it was administered several centuries before his time. But Sydenham was the first to point out its most important therapeutic property, its blood-restoring power. “To the worn out and languid blood,” he says, “it gives a spur or fillip whereby the animal spirits which before lay prostrate or sunk under their own weight are roused and excited.”...
The blood is composed of a fluid wherein float roundish red bodies, the blood corpuscles, which play a leading part in those tissue changes essential to life. Each corpuscle consists of a stroma permeated by a red fluid, haemoglobin, which has the remarkable property of readily combining with either oxygen or carbonic acid, but so loosely that under slightly altered conditions these gases are as readily separated from it. In the lungs the corpuscles, through their haemoglobin, take up oxygen which they carry to all parts of the body. But in the presence of the vital processes of disintegration and repair constantly going on in the tissues, the corpuscles yield up the oxygen they have brought, and supply an element necessary for these processes. Having got rid of the oxygen, the haemoglobin then unites with the carbonic acid produced by tissue disintegration, and the corpuscles thus reladen carry their burden Back to the lungs, and discharge there the carbonic acid, taking up anew a supply of oxygen. If the haemoglobiu of the blood fall below a certain standard, the supply of oxygen necessary to healthy tissue changes in brain, nerve, muscle, &c., becomes too limited, and the changes will be imperfectly performed; hence defective vitality, general or local. Now the ingestion of iron increases the haemoglobin supply when it is defective; it promotes the production of blood corpuscles, and causes each corpuscle to carry with it more haemoglobin; hence the health-giving power possessed by this metal. The exact method in which the increase in red colouring matter is brought about we do not know, but in the fact that iron forms an essential constituent of haemoglobin we have some clue to its utility.
Anaemia or spanaemia is the name given to that condition in which the red colouring matter of the blood is below the normal amount. It is indicated by pallor of skin and mucous membranes, and by a depressed condition of brain, of muscle, and of the tissues generally. A beating headache is often present, sustained mental or physical exertion is difficult, palpitation and breathlessness are sources of inconvenience; in the female the uterine functions are often in abeyance. By a chalybeate course we can usually restore to the blood its due supply of haemoglobin, and cause the gradual disappearance of all these symptoms.
It would be impossible here to enumerate all the special forms of spanaemia in which iron is prescribed. It will be sufficient to point out the leading conditions under which it may be given with every hope of advantage, and those in which it usually fails to do good. First of all, it is of marked benefit in the spanaemia of young females, which is often accompanied by a faint greenish or yellowish discoloration of the skill. Chlorosis is the name usually given to this condition. Here iron almost, unfailingly though slowly removes the pallor, breathlessness, and palpitation, increases mental and physical vigour, and restores the uterine functions. Where the blood has been impoverished by haeniorrhages, want of proper food, or exposure to bad hygienic conditions, iron rarely fails to improve its character, provided the causes of such impoverishment are removed. In convalescence from many illnesses, iron is employed with advantage, and it aids recovery from such constitutional diseases as rickets and scrofula by its restorative effect on the blood, sometimes too in syphilitic cachexia it is of service. On the other hand, in the obscure disease called pernicious anaemia, the cause of which is so far unknown, but in which the deficiency of haemoglobin is extreme, iron is rarely even of temporary service. It is generally useless too in the spanaemia attendant on advancing consumption where the temperature is high; some physicians indeed hold that in such cases it is injurious, because it increases temperature. In chronic diseases leading to spanaemia, where the cause of the poverty of blood is continuously present, iron is often of but little service. Such is the case in cancer and most of those emaciating ailments which tend naturally to a lethal termination. But in valvular disease of the heart, iron though not curative often helps to prolong life and relieve suffering, for by enriching the blood it spares the heart some of its labour, and at the same time strengthens the cardiac walls. In Bright’s disease too, which is often accompanied with bloodlessness, iron is a most valuable medicine in prolonging life even though incapable of saving it.
Hitherto we have spoken of iron only in its capacity of a strengthening agent acting through its power of stimulating the production of haemoglobin, but it may be beneficial in other ways. It is suppose! to augment the production in the blood of that active oxydizing agent ozone, but of this we have little or no proof; there is, however, considerable probability that the iron which exists as an albuminate in the blood serum has some direct tonic effect on the tissues through which it circulates; and the astringent preparations, such as the sulphate, are most effective in bracing the gastro-intestinal mucous membrane when it is relaxed.
Iron is of use iu some diseases of special organs and systems, partly perhaps from its general tonic effect, but in part too no doubt from some, local nutritive action which it has. In neuralgia, for example, it is sometimes curative, more certainly so, however, if combined with quinine. In chorea, or St Vitus’s dance, too, it is of value, especially when combined with arsenic. On the digestive organs chalybeates have at times a good effect, some forms of dyspepsia and diarrhoea being favourably influenced by them. Iron too is of service often in the nocturnal incontinence of children, and is often given as an emmenagogue. In gout, plethora, and most febrile ailments, the administration of iron is usually held to be injurious, but in erysipelas the administration of half drachm doses of the tincture of the perchloride of iron every four hours has been highly lauded, and Dr Russell Reynolds advocates the use of similar doses in acute rheumatisms. Iron is valued for the astringent effects of some of its preparations on parts with which they come in contact, as well as for its good effects on the blood and various organs after ingestion.
The tincture of perchloride of iron is used as a styptic to stop bleeding from the gums or from leech bites, or other slight haemoi·- rhages. Sometimes too it is of service locally applied in bleeding of a more serious character, but it is a strong irritant to the parts with which it comes in contact. One part of the tincture of the perchloride mixed with three of water is sometimes injected up the nostril to check persistent nose bleeding. Lint moistened with the tincture is also used as a plug for the same purpose. For stopping haemorrhage after confinement, the plan introduced by Dr Barnes of injecting a solution of perchloride of iron into the uterus is frequently followed with the greatest advantage. The perchloride and sulphate of iron may be given to check haemorrhage from the stomach, and these salts have likewise been used to decrease the discharge in gonorrhoea and leucorrhoea. The local application of the tincture of perchloride of iron in diphtheria has been highly recommended, and a very dilute solution is sometimes used as a rectal injection to destroy thread-worms.
As a medicine iron is used in many forms and combinations, and thirty-three of these arc described in the British Pharmacopoeia. The metal itself, finely divided, is often administered in 1 or 2 grain doses,—ferrum redactum the preparation is called,—and lozenges are made of it, each containing 1 grain of reduced iron. The vinum ferri or solution of iron in wine is probably the most ancient of all iron preparations. Of the oxides, the peroxide and the magnetic oxide are officinal. The former was in early times known under the name of saffron or crocus of iron, and was much used; but now more soluble preparations of iron are usually prescribed. Recently precipitated peroxide in a moist condition is one of the best antidotes for arsenical poisoning if given in quarter to half ounce doses. The carbonates of iron readily undergo oxidation unless mixed with sugar, which therefore enters into all the phar-macopoeial preparations of iron, the saccharated carbonate of iron, the pill of the carbonate of iron, and the compound iron mixture. Perhaps the most commonly used and the best known astringent preparations of iron are the combinations of this metal with vegetable acids, the ammonia citrate of iron and the tartrate of iron, which are given in 5 to 10 grain doses, the former too in the form of wine (vinum ferri citratis). The combination of citrate of iron and quinine is an exceedingly valuable preparation, and is given in 3 to 5 grain doses. The acetate of iron is somewhat astringent, but, though officinal, is very rarely used. The sulphate and perchloride of iron are powerful astringents, constricting the tissues with which they come in contact. Several preparations of these salts are officinal. Their use as local applications has been alluded to; internally they are given instead of the non-astringent chalybeates, when a tissue-bracing as well as a blood-restoring effect is desired. They are more constipating than the non-astringent chalybeates. The dose of the solution and tincture of perchloride of iron is from 5 to 20 minims. The sulphate is given in 1 to 3 grain doses. Iodide of iron, in the form of pill or syrup, is specially used iu cases of struma. The phosphate of iron and its syrup are of the greatest value when given to weakly and rickety children.
All the above-named iron medicines are officinal. Of those not mentioned in the Pharmacopoeia, two only need be alluded to—solution of dialysed iron, which of all preparations is perhaps the least liable to disagree with the stomach, and solution of the magnetic phosphate of iron in citric acid, commonly known as Lightfoot’s steel, one of the most agreeable of the acid solutions of iron.
Many mineral waters contain iron. In most it exists as a carbonate, but in one of the springs at Harrogate as chloride. Chalybeate waters are in suitable cases the most effective of blood tonics.
Ingestion of iron in all forms causes the stools to become black. This arises from the fact that, when iron is taken, but little is absorbed; the rest passing into the intestinal canal is converted into the black sulphide by the sulphuretted hydrogen present there. The discoloration is devoid of all significance. The evil effect of iron preparations on the teeth has been much exaggerated. The acid chalybeates, if taken in a concentrated form, may indeed do harm, and all iron medicines tend to blacken the teeth somewhat, but by washing the mouth out with water after taking them the possibility of injury is readily prevented.
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ברזל; occurs first in Gen. iv, 22, and afterward frequently; and the Chaldee פרזל, in Dan. ii, 33, 41, and elsewhere often in that book; σίδηρος, Rev. xviii, 12, and the adjectives, Acts xii, 10; Rev. ii, 27; ix, 9; xii, 5; xix, 15; a well known and very serviceable metal. The knowledge of working it was very ancient, as appears from Genesis iv, 22. We do not, however, find that Moses made use of iron in the fabric of the tabernacle in the wilderness, or Solomon in any part of the temple at Jerusalem. Yet, from the manner in which the Jewish legislator speaks of iron, the metal, it appears, must have been in use in Egypt before his time. He celebrates the great hardness of it, Lev. xxvi, 19; Deut. xxviii, 23, 48; takes notice that the bedstead of Og, king of Bashan, was of iron, Deut. iii, 11; he speaks of mines of iron, Deut. viii, 9; and he compares the severity of the servitude of the Israelites in Egypt to the heat of a furnace for melting iron, Deut. iv, 20. We find, also, that swords, Num. xxxv, 16, axes, Deut. xix, 5, and tools for cutting stones, Deut. xxvii, 5, were made of iron. By the “northern iron,” Jer. xv, 12, we may probably understand the hardened iron, called in Greek χάλυψ, from the Chalybes, a people bordering on the Euxine sea, and consequently lying on the north of Judea, by whom the art of tempering steel is said to have been discovered. Strabo speaks of this people by the name of Chalybes, but afterward Chaldæi; and mentions their iron mines. These, however, were a different people from the Chaldeans, who were united with the Babylonians.
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IRON CONTD hand the same term is often used to imply the softening or annealing only of the tool.
In the act of hardening, steel becomes specifically lighter to an extent varying with the temperature attained before cooling, the composition of the steel, and its form and dimensions, and according as it has been rolled or otherwise worked before treatment; thus Elsner found a specimen of cast steel had the specific gravity 7’9288 before hardening, and 7 ’ 6578 after (both at 11° C.), indicating an expansion in volume of about 3 - 5 per cent. Similarly Hinman found expansions of 2 - 6 to 3 - 5 per cent, for blister steel; and Hausmann found for a very hard steel and for a soft welding steel expansions of l - 7 and 0'8 per cent, respectively. The expansion, however, is not uniform in all directions; thus Caron found that a hammered steel bar 20 centimetres long and 1 centimetre square in section altered after repeated hardenings to the following extent in percentages of the original dimensions :— [table]
whilst with rolled steel there was an increase in length of 2’25 per cent, and no change in the other dimensions....
On thoroughly annealing hardened steel it recovers the original, dimensions possessed before hardening; evidently therefore when a large steel tool is hardened, since the inner portion cannot possibly become cooled at the same rate as the outer film, a kind of strain must be developed amongst the particles; for, whilst the rapid chilling of the outer portion causes that part to occupy a larger volume than it otherwise would, this is not effected to so large a relative extent with the inner portions. The opposite result is necessarily produced during annealing. Accordingly, in the process of tempering steel goods, cracking and splitting or “buckling” and otherwise getting out of shape are inconvenient results that are apt to happen, especially when all parts of the surface are not equally and simultaneously heated or chilled, a result difficult to bring about with articles of certain shapes; the hardening process may in such cases be more safely effected by heating the article up gradually in a fluid bath such as melted lead (or in some cases oil) and then chilling in a cool fluid bath, preferably of oil; whilst the annealing may be performed by allowing the fluid in which the article is slowly heated up to cool down again spontaneously when the requisite temperature is attained. For special articles, c.y., saws, a particular manipulation is requisite to avoid buckling; in some cases the annealing of a flat plate, e.g., a circular saw, is effected between two solid flat masses of iron, which keep the plates from getting out of shape whilst cooling. In some instances when the point only of an article is required to be tempered, e. g., certain kinds of chisels, the whole mass is heated red hot and the point dipped into water or oil to harden it; on taking out, the heat from the body of the hot article is rapidly conducted to the point; as soon as its temperature is sufficiently raised the body is somewhat cooled by a short immersion so as to reduce the temperature of the whole approximately to uniformity, and then the article is allowed to cool altogether slowly; so that the hardening and annealing are effected by one heating only. For articles the temper of which requires to be somewhat exactly determined, the temperature attained is judged of by the tint of the iridescent film of oxide which forms on the surface (previously brightened) during the heating; the higher the temperature the thicker the film, the colours and temperatures being approximately as follows :— [table]
For instance, if a saw is to be tempered at a full blue it is heated over a clear fire or a mass of red hot iron or in a sand bath until the tint appears on the brightened surface, when it is allowed to oool. In many cases the tempering of tools is effected with sufficient accuracy without brightening them, by coating them with tallow, oil, or some similar composition, and then heating over a lamp or amass of hot metal until the tallow, &c., begins to decompose; with sufficient experience as to the size of the article, the mode of heating, and the character of the decomposition set up, much the same results are arrived at as when the colour is watched on the brightened surface. In some instances the requisite temper is given by one operation only, the point of the article to be hardened (a drill, say) being coated with tallow and heated in a flame until the tallow decomposes rapidly, and then plunged into a mass of tallow to chill it; the point is thus rendered harder than the body of the drill. By heating the point of a small tool nearly white hot and plunging it into a stick of sealing wax for a second, and then into another part of the wax, and so on till cold, steel may be made so hard as to be readily capable of boring into similar steel hardened in the ordinary way.
Instead of determining the temperature of the object to be annealed by the tint developed on it, various fusible alloys may be used, a series of such being placed in the annealing bath, so that by observing which are fluid the temperature is known approximately. Parkes gives the following compositions of lead-tin alloys for this purpose :— [table]
The first five of these alloys consequently correspond to the various yellow shades; the next three to brown, brown and purple spots, and purple; and the last four to the blue shades.
43. Strength and Tenacity of Iron and Steel.— Independently of the additional strength communicated to iron by the presence of small quantities of carbon, producing steels or so-called steels of various kinds, a considerable increase in this property is brought about by the removal of portions of cindery matter by fusion. Wrought iron that has simply been welded, reheated, and rolled a given number of times is, caeteris paribus, less tenacious than iron from which complete fusion has removed the films of silicate, &c., enveloping the component layers and fibres of the welded material, and preventing their complete union together. Thus the best qualities of weld iron, containing usually about 0 - 2 to 0 - 3 per cent, of carbon, possess a tensile strain of from 20 to 30 tons per square inch, whilst mild “steels” and ingot irons are usually considerably higher in this respect, viz., from 30 to 40 tons per square inch; harder steels of higher carbon percentage are proportionately stronger. The following numbers may be quoted, representing tensile strains in tons per square inch. [table]
Steel wire of as high a breaking strain as 206,170 lb, or 92 tons, per square inch section, has been drawn by Johnson and Nephew (Manchester), whilst wire of tensile strength of 70 to 80 tons per square inch is readily procurable. According to Collingwood, galvanizing increases the strength of freshly drawn wire by about 15 per cent., whilst ungalvanized wire has been found to gain nearly 5 per cent, by merely being allowed to remain at rest for a week or so; the increase of strength in each case appears to be simply due to internal adjustment of the strains produced during drawing.
It does not necessarily follow that the resistance to percussive force exhibited by a given sample of metal will be in the ratio of its tensile strength. Thus phosphorus when present together with only minute quantities of carbon (forming the so-called “phosphoric steels ”) does not very materially decrease the tensile strength, such steels containing 0 ’ 3 per cent, of phosphorus being often but little inferior to soft non-phosphorized steels in this respect; but when tested by a “falling weight” (a mass of known weight falling once or oftener from a known height upon the centre of the bar or rail firmly gripped in supports a known distance apart) the phosphorized metals generally show themselves considerably inferior to the non-phosphorized ones. The same remark applies to silicon. According to
Dudley the effect of phosphorus, silicon, and carbon in hardening iron and making it less capable of resisting percussion are nearly in the proportions of 3, 2, and 1 relatively to one another. The presence of manganese diminishes this deleterious effect of non-metals; whilst, if more than minute quantities of carbon be present, the tensile strength as well as the resistance to percussion is greatly diminished by the additional presence of phosphorus or silicon in proportions beyond certain small limiting amounts. Accordingly it is the usual practice to test rails, bars, &c., not only by the determination of the breaking strain for tensile force (measured by pulling asunder, preferably by hydraulic power, a bar turned to known definite dimensions, and made into the shape of fig. 65), but also by a falling weight,—a “monkey” (somewhat like a pile driver) being raised to a known height and let drop upon the rail.
The particular tests applied in different instances vary much; for instance, some little while ago the official falling weight test for Bessemer rails at Gratz (Austrian South Railway Company’s Works) was to permit a weight of 1000 kilos (about a ton) to fall from a height of 15 feet upon the centre of the rail supported by two rests 3 feet apart, any amount of bending being allowed, but not fracture, whilst a test for elasticity or resistance to permanent deflexion was applied by placing a weight of 17,500 kilos on the middle of the rail similarly supported. The North-Eastern Railway (England) similarly at one time tested rails by allowing a weight of 1800 lb to fall from 4 feet height, the number of blows requisite to produce rupture and the permanent bending produced by each being noted. In other instances the test applied has been a ton weight falling a greater height, such as 20 feet or even 30 feet, the rail being required to stand one such blow only, or a succession, the particular details of the test to be applied being usually specified in each particular case; thus the Midland Railway Company has tested steel rails by allowing a weight of 1 ton to fall three times from a height of 12 feet, the supports being 4 feet asunder.
In just the same way as regards the determination of tensile strength, the dimensions of the piece to be tested (6 inches, 8 inches, 10 inches long, &c.) are usually specified, and the strain which the metal will just stand without becoming permanently elongated {limit of elasticity) determined, as well as the total strain requisite to produce rupture, together with the “ductility” or amount of permanent extension of the test piece and the diminution in section of the bar at the point of rupture. Thus for instance the following numerical data were obtained by Kirkaldy with a particular specimen of West Cumberland Bessemer steel plate, three pieces being tested, each 10 inches long, and respectively ∣, ⅜, and ∣ inch in thickness. [table]
These numbers illustrate, amongst other things, the effect upon the final values produced by variations in the diameter of the test pieces; the shorter and thicker the piece the greater in amount is the permanent extension. In calculating the rupturing strain per square inch, the dimensions of the metal as originally employed before permanent alteration was brought about are employed; by taking the diminished area at the point of fracture as the section, a much higher value is obtained as the tensile strength per unit area of the extended metal. Tempering steel greatly increases its breaking strain and limit of elasticity, but decreases the permanent extension; thus the following values represent certain results obtained with Creuzot steels of the A class, in tons per square inch (see Engineering, 1875, p. 119). [table]
In making a contract for the supply of steel of a particular quality, the details of the tests of strength to be applied should consequently be duly set forth; for instance, a short time ago the French Government required certain steel navy tubes, of which the limit of elasticity and breaking strain tested in a particular way were respectively to be 21 and 38 tons per square inch. Similarly in the construction of the Mississippi great bridge the cast steels used were contracted to be of the following qualities :—“To be of crucible cast steel; the staves of the tubes to stand a compressive strain of 60,000 and a tensile strain of 40,000 lb per square inch section without permanent set, and to stand a tensile strain of 100,000 lb per square inch without fracture. Modulus of elasticity to be between 26 and 30 million lb, preferably nearer the lower limit, and as constant as possible; bars of the same modulus to be selected for the tubes, so that each side shall have same power of resistance; each bar to be tested and modulus stamped on it. Steel pins, rods, bolts, eyewashers, rivets, &c., and the ⅛ inch steel plates for enveloping the staves to stand a tensile strain of 40,000 fb per square inch without permanent set, and an ultimate tensile strain of 100,000 lb without fracture.”
Practical tests of the capability of metal to stand bending double or through some given angle, or twisting round and round in the cold without fracture are often applied, as are also tests of the capability of being bent hot, forged, welded, &c. A test as to the power of resisting repeated bending strains backward and forward through a given angle is sometimes applied; a particular mechanical arrangement for effecting this has been described by Olrick.
James Price has constructed a machine for testing rails as to durability under rolling wear and tear, consisting of a pair of metal rollers 5 feet in diameter and 16 inches wide, weighing 45 cwts. each, supporting a frame weighing 6⅜ tons, connected with a centre boss and vertical axle, so that the rollers are driven round in a circle, one bearing with 5 the other with 6 tons pressure; the rails to be tested are bent into a circle or preferably a polygon, to equalize the wear of the rollers, which are driven over them at a speed of 13 or 14 miles per hour until the rails are broken or wear out.
It by no means follows that the rail which possesses the greatest tensile strength will resist wear and tear and rolling friction best, although this might be anticipated if, other things being equal, increased tensile strength corresponds to greater hardness; on the other hand, experience does not always indicate that the most carbonized rails last the longest, although the superiority of ingot metal (Bessemer steel, &c.) over weld iron (not fused) rails is well demonstrated; it is probable that the interposed film of cinder between the metallic fibres in the latter case greatly facilitates the destruction and wearing away of the upper surface, just as the accumulation of dust and sand on the rail between the passage of consecutive trains, especially conjoined with moisture, conduces to mechanical abrasion. Price Williams has calculated from the results of various British lines that the average tonnage lives of wrought iron and Bessemer rails (i.e., the traffic in tons requisite to wear away f inch of the head of the rail) are respectively close to 17⅜and 161 million tons, the latter being thus more than nine times as lasting as the former.
Numerous observations have been made on the effect on the strength of iron and steel of punching and dialling holes, of notching and otherwise removing part of the surface, and of shearing, with the general result of indicating that the disturbance produced in the relative positions of the constituent particles by forcibly punching and shearing in the cold materially decreases the strength of a bar or plate (apart from the actual removal of substance); but that drilling does not effect the strength in the same way (see various papers in the Journal I. and S. Inst., Iron, and Engineering during the last few years). Annealing restores the strength to a considerable extent; if the plates be punched whilst red hot the annealing takes place spontaneously.
The strengthening effect upon soft steels and ingot irons of hardening by heating and plunging into oil is often very marked, the tendency to crystallinity observable in large masses of cast metal being thus largely removed. A valuable paper 0 on the causes and effects of hardening iron and steel, by Professor Akermann, is to be found in the Journal I. and 8. Inst., 1879, 504; whilst the Research Committee of the Institution of Mechanical Engineers has recently issued reports containing much information on thiä subject.
Effect of Temperature on the Strength of Iron and Steel. —Many observations on this point have been made by different experimenters, with the general result of indicating that at 0° C. and below the tensile strain and resistance to percussion of iron and steel bars, rods, &c., are substantially the same as at the average ordinary temperatures of 15° to 20°, but that what difference there is is usually in the direction of diminution in strength; the numerical values obtainable are considerably variable with the composition of the metal, Ac.; thus Webster finds that a severe cold of - 15° C. does not affect the tensile strain of wrought iron and steel, although it slightly increases the ductility by about 1 per cent, with iron and 3 per cent, with steel; the power of resisting transverse strain is, however, some 3 per cent, lower, whilst the flexibility and the resistance to rupture by impact are reduced by the following amounts :— [table]
A committee of engineers appointed by the Russian Government for the purpose of examining carefully into this question has recently found that, when the amount of phosphorus, silicon, and carbon in Bessemer and Siemens-Martin steel rails exceeds jointly about 0 ’ 54 (varying from 0 ’ 44 to 0 ’ 67) per cent., the rails are decidedly more brittle at temperatures near to - 20° C. than at the ordinary temperature ( 4- 10° to 20°); whilst the effect of low temperature in producing brittleness is not marked when the phosphorus, silicon, and carbon jointly amount to only about 0 ’ 41 (0 , 37 to 0 ’ 55) per cent. Expressing the amounts of non-metals on the scale proposed by Dudley (3 parts of carbon, 2 of silicon, and 1 of phosphorus being considered as equivalent to one another, so that a rail containing carbon = 0'30, silicon — 0 - 20, phosphorus = 005, would be equivalent to one containing phosphorus = 0 ’ 25), these results may be expressed as follows: when the percentages of carbon, silicon, and phosphorus are jointly equivalent to an average of 0 ’ 19 per cent, of phosphorus, the effect of low temperatures is not marked; but when they are equivalent to an average of 0’31 per cent, of phosphorus, the rails are more brittle at temperatures near - 20° than at ordinary average temperatures near to + 15°.
Breakages of axles, crankshafts, pumprods, &c., exposed to strains and vibration appear to be more common in frosty weather than at other seasons of the year; it is considered by many that exposure to vibration, &c., and low temperature simultaneously tend to diminish tenacity and set up a brittle structure in a way not observed when only one of the two causes alone acts; direct evidence on this point is, however, wanting. It is noticeable that large masses of cast metal (cast iron, true steel, or ingot metal) if cooled too quickly are apt to have the internal portions in a high state of tension or strain; for the outer portion, when solidified, prevents the contraction taking place that would otherwise ensue during the solidification and cooling of the inner portion; hence the amount of extra strain requisite to produce rupture is much diminished, so that the want of elasticity of bearings, foundations, &c., connected with the almost rigid ground during hard frosts in certain cases causes the strain applied during use to exceed the reduced amount which the metal can then bear without fracture. Chilled castings, case hardened iron, and tempered steel, moreover, are affected by low temperatures in another way; the outer harder portions do not expand at exactly the same rate as the inner softer parts; and consequently alteration of temperature produces such variations in the internal strain as in some cases to lead to fracture either spontaneously or by the superaddition of the strain due to ordinary use. On the whole it appears that no clear evidence is as yet extant proving that vibration either alone or concurrently with low temperature does actually cause a brittle crystalline structure to be...
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IRON MASK. The Man in the Iron Mask is the name by which a French state prisoner, whose identity has given rise to much curious inquiry, is universally known. The facts established by contemporaneous evidence respecting this mysterious personage, who died in 1703, were, until a modern writer largely added to them, neither numerous nor of very great importance. Enough indeed is related to show that even in his lifetime the veiled prisoner had become an object of curious mystery. Other instances occur, however, of captivity under like conditions; and nothing in the treatment of the Mask proves that he was a personage of rank and importance. It has been indisputably shown that it was no uncommon practice, especially in the reign of Louis XIV., to isolate human beings and keep them immured, their very features being carefully hidden, and that the victims were persons of all conditions. Though one or two efforts had been previously made to find out the name of the unknown prisoner, Voltaire was the first writer of note to give form and life to the vague traditions that had been current about the Mask; and we may probably ascribe to his suggestive account the increased importance which since his time the subject has been supposed to possess. In his Age of Louis XIV. the historian hinted that the Mask was a person of high rank; and he graphically described how this mysterious being endeavoured to commune with the outer world by throwing out, on the shore of Sainte Marguerite, from the grated window of his gloomy dungeon, a piece of fine linen, and a silver plate, on which he had traced some strange characters to revêal a horrible tale of misfortune. This work was published in 1751, nearly fifty years after the death of the Mask; and from this time the problem who he was has ...been investigated with no little diligence. The editor of the Philosophic Dictionary suggested that he was an illegitimate son of Anne of Austria, born in 1626; and in 1790 he was identified, in the Memoirs of Cardinal Richelieu with a supposed twin brother of Louis XIV., put out of the way by the great Cardinal to avoid the ills of a disputed succession. As early as 1745 the Mask was said, by an anonymous writer, to have been the count of Vermandois, one of the bastards of Louis XIV.; in 1759 M. Lagrange-Chaucel endeavoured to prove that he was the duke of Beaufort, a hero of the Fronde; a few years afterwards M. St Foix conjectured that he was the duke of Monmouth, the English pretender of 1685; and others have laboured to show that he was either a son of the Protector Cromwell, or Fouquet, the minister of Louis XIV., or Avcdick, the Armenian patriarch, whose treacherous imprisonment by the ambassador of France was one of the worst acts of that unscrupulous king. The claim, finally, of Ercolo Mattioli, a diplomatic agent of the duke of Mantua, was put forward in 1770, and since that time has found zealous advocates in MM. Roux-Fazillac, Delort, Topin, and in the late Lord Dover; indeed, until lately it was generally thought that Mattioli was the mysterious captive.
The claims, however, of none of these can stand the test of the searching inquiry which recent discoveries have made possible. Voltaire does not inform us who the Mask was; his hint that he was an exalted personage is at variance with a remark of his on the same subject in a later work; and as for the tale of the attempts made by the Mask to divulge his name and fate, these have been traced to a Huguenot pastor, imprisoned in the islands of Sainte Marguerite. There is no evidence that the illegitimate child of Anne of Austria, or the twin brother of Louis XIV. ever existed. Fouquet died in 1680, the count of Vermandois in 1683, and the duke of Beaufort in 1689; Monmouth fell under the axe of the headsman; Avcdick was not imprisoned until 1706. The case made on behalf of Mattioli also breaks down when carefully sifted. Mattioli was certainly imprisoned at Pignerol, and that for a considerable time; he was also long under the care of Saint Mars; and he was detained at the Sainte Marguerites, in the custody of the same jailer. But on the other hand the Mask is never named in the numerous documents that refer to him; he was certainly imprisoned at Exiles; and he was brought from the Sainte Marguerites, and died in the Bastille; whereas Mattioli’s name occurs not seldom in the correspondence of Saint Mars; he cannot be traced to Exiles; and it is almost certain that he died at the Sainte Marguerites in 1694.
Is it impossible, then, to fix the identity of the unknown Mask? The latest writer upon the subject is Μ. Jung, a French staff officer, and his diligent investigations have brought us perhaps very near the solution of the problem. He appears to have fully proved that the prisoner of 1698—beyond question the mysterious Mask—had for many years been guarded by St Mars; that he had long been known as “your ancient prisoner,” “your prisoner of twenty years standing”; and that at the Sainte Marguerites he was jealously watched with precautions nearly of the same kind as those afterwards taken at the Bastille. He has shown, moreover, that this very prisoner was, in 1687, removed to the Sainte Marguerites from Exiles, always under the eye of the same jailer, and that, too, with the care and secrecy observed in the journey to the Bastille; and, finally, he has traced the captive to Pignerol, still in the hands of the relentless St Mars, where, in 1681, we find him designated as one of the “two prisoners of the Lower Tower,” apparently for some years in confinement. This prisoner, too, is never once named, which, as we have seen, was the case with the Mask. On the whole it would seem that Μ. Jung has established the identity of the object of our search with this unknown person. He goes, however, a great deal further, and endeavours to find out the name and the history of the prisoner of the Lower Tower of Pignerol. His theory is that he was a criminal who probably played a prominent part in one of the numerous poisoning plots which disgraced the reign of Louis XIV.; and he identifies him with a Lorraine gentleman who seems to have belonged to a murderous band of conspirators against the life of the king, and who, being then arrested at Peronne, was lodged in the Bastille in 1673, and thence taken, he makes out, to Pignerol. His narrative abounds in interest, but he has adduced no valid proof to connect the supposed prisoner captured at Peronne with the prisoner of 1673; and he has not given us anything like evidence to associate this last-named person with either of the prisoners of the Lower Tower at Pignerol, or even to show that he reached that fortress. Besides, he has not ascertained the identity of these two prisoners. The mystery of the identity of the Mask thus remains unsolved; but the field of inquiry has been greatly narrowed, and further investigation will not improbably discover this strange historical secret. (W. O. Μ.)
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IRON-WOOD is the name applied to several kinds of timber, the produce of trees from different parts of the tropics, and belonging to very different natural families. Usually the wood is extremely hard, dense, and darkcoloured, and sinks in water. The true iron-wood of the East Indies and Malay archipelago, of which anchors are often made, seems to be the Metrosideros vera of Rumphius, a tree belonging to the Myrtaceae, and formerly extensively used in China, Japan, and the Moluccas. Several species of Sideroxylon lfjapotaceae) also yield ironwood, Sideroxylon cinereum or Bojemanum, D. C., being the bois de fer blanc of Africa and Mauritius....
West Indian iron-wood is the produce of Colubrina reclinata and C. ferrugina, Ad. Br. (Rhamnaccae), and of Aegiphila mar· tinicensis, Linn. (Verbenaceae). Ixοra (Sidcrodendrori) triflorwm, Vahl. (Rubiaceae), is the bois de fer of Martinique, and Zanthoxy∙ lum Pterota, H. B. K. (Rutaceae), is the iron-wood of Jamaica, while Robinia Ponacoco, Aubl. (Lcgumwosae), is described as the iron-wood of Guiana. The iron-wood of Ceylon is the produce of Mesua ferrea, Linn. (Guttifcrae). The endemic bois de fer of Mauri·» tius, once frequent in the primeval woods, but now becoming very scarce, is the Stadtmannia Sideroxylon, I). C. (Sapindace ae}, while the Cossignya pinnata, Lam., is known as the bois de fer de Judas. Coccoloba grandifolia and C. pubescens (Polygonaceae) yield a kind of West Indian iron-wood. Muba buxifolia, Pers. (Ebenaceaej, yields a variety of iron-wood which is used at Tavoy in Burmah to make anchors for large boats. Tasmanian iron-wood is the produce of Notelaea ligustrina (Oleaceae), and is chiefly used for making ships’ blocks. The iron-wood or lever-wood of North America is the timber of the American hop hornbeam, Ostrya νirginica (Cιιpu- liferae). In Brazil Apuleia ferrea, Mart., and Caesalpinia ferrea, Mart., yield a kind of iron-wood, called, however, the Pao ferro or false iron-wood.
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